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| 1872 | Molteno, John Charles |  |
| 1st Dec Appointed Prime Minister of the Cape Colony
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| 1878 | Sprigg, John Gordon | |
| 8th May Appointed Prime Minister of the Cape Colony, 1st term
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| 1881 | Scanlen, Thomas Charles | |
| 9th May Appointed Prime Minister of the Cape Colony
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| 1884 | Upington, Thomas | |
| 13th May Appointed Prime Minister of the Cape Colony
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| 1886 | Sprigg, John Gordon | |
| 25th Nov Appointed Prime Minister of the Cape Colony, 2nd term
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| 1904 | Jameson, Leanders Starr | |
| Appointed Prime Minister of Sth Africa
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| 1907 | Botha, Louis | |
| 4th Mar Appointed Prime Minister of the Transvaal
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| 1908 | Smuts, Jan Christian | |
| Appointed Minister of Defense
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| Appointed Minister of Mines
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| Appointed Minister of the Interior
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| 1910 | Botha, Louis | |
| Appointed Prime Minister of the Transvaal
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| 1910 | Hertzog, James | |
| Appointed Minister of Justice & Native Affairs, serves under Botha
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| 1910 | Malan, Francois Stephanus | |
| Appointed Minister of Education
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| 1915 | Botha, Louis | |
| Appointed Prime Minister of Sth Africa, 2nd term
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| 1918 | Malan, Francois Stephanus | |
| Appointed Acting Prime Minister of SouthAfrica
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| 1919 | Smuts, Jan Christian | |
| Appointed Prime Minister of SouthAfrica, 1st term
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| 1924 | Hertzog, James | |
| Appointed Prime Minister of SouthAfrica, 1st term
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| 1924 | Malan, Daniel Francois | |
| Appointed Minister of Education
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| Appointed Minister of National Health by Hertzog
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| Appointed Minister of the Interior by Hertzog
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| 1933 | Hertzog, James | |
| Appointed Prime Minister, 2nd term, shares power with the United Party of Smuts
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| 1933 | Smuts, Jan Christian | |
| Pretoria Africa Appointed Deputy Prime Minister
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| Appointed Minister of Justice
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| 1936 | Hofmeyr, Jan Hendrik | |
| Appointed Minister of Labour & Mines
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| 1938 | Hertzog, James | |
| 18th May Confirmed in power after SouthAfrican elections
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| 1939 | Hofmeyr, Jan Hendrik | |
| Appointed Deputy Prime Minister
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| Appointed Minister of Education
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| Appointed Minister of Finance
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| 1939 | Smit, Douglas | |
| Appointed Secretary for Native Affairs
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| 1939 | Smuts, Jan Christian | |
| 5th Sep Appointed Prime Minister of Sth Africa, 2nd term
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| 1939 | Strauss, Jacob Gideon Nel | |
| Appointed Minister for Agriculture & Forestry
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| 1941 | Hofmeyr, Jan Hendrik | |
| Appointed Deputy Prime Minister
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| 1943 | Smuts, Jan Christian | |
| Appointed Prime Minister of SouthAfrica, 3rd term
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| 1948 | Malan, Daniel Francois | |
| 3rd June Appointed Prime Minister of Sth Africa
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| 1950 | Verwoerd, Hendrik Frensch | |
| Appointed Minister of Native Affairs
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| 1954 | Strijdom, Johennes Gerhardus | |
| Appointed Prime Minister of Sth Africa, 5th Prime Minister of Sth Africa
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| 1958 | Verwoerd, Hendrik Frensch | |
| 2nd Sep Appointed Prime Minister of SouthAfrica
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| 1961 | Botha, Pieter | |
| Aug Appointed Minister of Coloured Affairs
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| Aug Appointed Minister of Housing
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| 1961 | Vorster, Balthazar Johannes | |
| Aug Appointed Minister of Justice
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| 1966 | Donges, Theophilus | |
| 6th Sep Appointed Prime Minister of SouthAfrica, acting
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| 1966 | Vorster, Balthazar Johannes | |
| Appointed Prime Minister of SouthAfrica
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| 1994 | Slovo, Joe | |
| Appointed Minister of Housing
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| 2004 | Dlamini-Zuma, Nkosazana | |
| Appointed Foreign Minister
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| 2004 | Manuel, Trevor | |
| Appointed Minister of Finance
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